Letian Dou Group

Aihui and Kang’s work on highly efficient halide perovskite light-emitting diodes via molecular passivation has been published in Angewandte Chemie International Edition. Big congratulations!! Read the story here.

Metal halide perovskites are promising for applications in light‐emitting diodes (LEDs), but still suffer from defects‐mediated nonradiative losses, which represent a major efficiency‐limiting factor in perovskite‐based LEDs (PeLEDs). Reported here is a strategy to synthesize molecular passivators with different anchoring groups for defects passivation. The passivated perovskite thin films exhibit improved optoelectronic properties as well as reduced grain size and surface roughness, thus enable highly efficient PeLEDs with an external quantum efficiency of 15.6 %. Our results provide new fundamental insights into the role of organic molecular passivators in boosting the performance of PeLEDs.

Akriti, Enzheng, and Stephen’s paper on Layer-by-Layer Anionic Diffusion in Two-Dimensional Halide Perovskite Vertical Heterostructures has been published in Nature Nanotechnology. Big congratulations!

Anionic diffusion in a soft crystal lattice of hybrid halide perovskites affects their stability, optoelectronic properties and the resulting device performance. The use of two-dimensional (2D) halide perovskites improves the chemical stability of perovskites and suppresses the intrinsic anionic diffusion in solid-state devices. However, a fundamental understanding of the role of organic cations in inhibiting anionic diffusion across the perovskite–ligand interface is missing. Here we demonstrate the first quantitative investigation of the anionic interdiffusion across atomically flat 2D vertical heterojunctions. A ‘quantized’ layer-by-layer diffusion model is proposed to describe the behaviour of the anionic migration in 2D halide perovskites. Our results provide important insights into the mechanism of anionic diffusion in 2D perovskites and provide a new materials platform with an enhanced stability for heterostructure integration.

This is is highlighted in Purdue Chemical Engineering newsroom, and many media.

Ke’s paper on Organic Cation Engineering for Vertical Charge Transport in Lead-Free Perovskite Quantum Wells has been published in Small Science. Congratulations! Read the story here.

Jee passes his qualifier exam and now becomes a PhD candidate. Congratulations!

Blake’s work on skin-inspired mechanically self-healing perovskite solar cells has been published in Cell Reports Physical Science. Congratulations! Read the story here.

We are guest editing a special issue of “Halide Perovskites for Photonics and Optoelectronics” in Optical Materials Express together with Prof. Xiwen Gong @ University of Michigan, USA; Prof. Sergey Makarov @ ITMO University, Russia; Prof. Barry Rand @ Princeton University, USA; and Prof. Yongsheng Zhao @ Institute of Chemistry, CAS, China. Looking forward to your submissions!

The group welcomes two new graduate students: Qixuan Hu and Xi Wang. Qixuan got his BS in Chemical Engineering from University of Maryland in 2020, he will work on polymers and materials chemistry; Xi got his BS in Materials Science and Engineering in 2020, he will work on perovskite materials and devices. Welcome to the group!

Our work on halide perovskite solar cell stability and manufacturing is recognized by American-Made Solar Prize, a contest organized by Department of Energy and National Renewable Energy Laboratory. The team is lead by Prof. Letian Dou, Prof. Brett Savoie and Prof. Jianguo Mei. Watch an excellent movie prepared by Aidan: https://www.youtube.com/watch?v=UwS5OkQ6yZQ&feature=youtu.be

Enzheng’s review paper on halide perovskite heterostructures have been published in Accounts of Materials Research. This work is highlighted as an inside cover. Congratulations! This is a summary of our recent work in the past three years. Credits go to all my group members and collaborators. And a big thank you to Prof. Jiaxing Huang for the invitation!

Akriti is selected to receive the Arvind Varma Fellowship in recognition of her great contribution in fundamental study of anion interdiffusion in perovskite heterostructures and her leadership in teaching and mentoring. Only 1 recipient each year from the school, in memorial of Prof. Arvind Varma, a giant in chemical engineering. Congratulations!